In June 2011, the International Union of Pure and Applied Chemistry (IUPAC) published a report which assigned priority for discovery of elements 114 and 116 to the Dubna-Livermore collaboration:
"Priority for the discovery of the elements with atomic number 114 and 116 has been assigned, in accordance with the agreed criteria, to collaborative work between scientists from the Joint Institute for Nuclear Research in Dubna, Russia and from Lawrence Livermore, California, USA (the Dubna-Livermore collaborations). The discovery evidences were recently reviewed and recognized by a IUPAC/IUPAP joint working party. IUPAC confirmed the recognition of the elements in a letter to the leaders of the collaboration.
The IUPAC/IUPAP Joint Working Party (JWP) on the priority of claims to the discovery of new elements has reviewed the relevant literature pertaining to several claims. In accordance with the criteria for the discovery of elements previously established by the 1992 IUPAC/IUPAP Transfermium Working Group, and reiterated by the 1999 and 2003 IUPAC/IUPAP JWPs, it was concluded that "the establishment of the identity of the isotope 283Cn by a large number of decaying chains, originating from a variety of production pathways essentially triangulating its A,Z character enables that nuclide's use in unequivocally recognizing higher-Z isotopes that are observed to decay through it." From 2004 Dubna-Livermore collaborations the JWP notes: (i) the internal redundancy and extended decay chain sequence for identification of Z = 287114 from 48Ca + 242Pu fusion (Oganessian et al. Eur. Phys. J. A 19, 3 (2004) and Phys. Rev. C 70, 064609 (2004)); and (ii) that the report of the production of 291116 from the fusion of 48Ca with 245Cm is supported by extended decay chains that include, again, 283Cn and descendants (Oganessian et al. Phys. Rev. C 69, 054607 (2004)). It recommends that the Dubna-Livermore collaborations be credited with discovery of these two new elements.
A full synopsis of the relevant experiments and related efforts is presented in a technical report published online in Pure and Applied Chemistry on 1 June 2011. With the priority for the discovery established, the scientists from the Dubna-Livermore collaborations are invited to propose a name for the two super-heavy elements, elements 114 and 116. The suggested names will then go through a review process before adoption by the IUPAC Council.
Review of the claims associated with elements 113, 115, and 118 are at this time not conclusive and evidences have not met the criteria for discovery."
The report can be found on the IUPAC web site.
On Dec. 1, 2011, the IUPAC President, Prof. Nicole Moreau, announced the proposed names of the new elements at the closing ceremonies for the International Year of Chemistry (celebrated during 2011) in Brussels, Belgium, starting a 5 month public comment period before the names can be accepted officially by the IUPAC. This was announced here:
The process of discovery and naming of an element is a long one. Experiments first glimpsed element 114 in 1998 and element 116 in 2001, with continuing experiments satisfying the discovery criteria in 2004 and 2006, and confirmatory experiments by other laboratories in 2007 – 2010.
The collaboration is led by Dr. Yuri Ts. Oganessian. The participants in these experiments include:
Dubna: Yu.Ts. Oganessian, V.K. Utyonkov, F.Sh. Abdullin, A.N. Polyakov, I.V. Shirokovsky, Yu.S. Tsyganov, R.N. Sagaidak, G.G. Gulbekian, S.L Bogomolov, B.N. Gikal, A.N. Mezentsev, V.G. Subbotin, A.M. Sukhov, A.A. Voinov, K. Subotic, G.K. Vostokin, M.G. Itkis, V.I. Zagrebaev, R.I. Il’kaev, S.P. Vesnovskii
LLNL: K.J. Moody, D.A. Shaughnessy, M.A. Stoyer, J.M. Kenneally, C.A. Gregorich, J.H. Landrum, R.W. Lougheed, J.B. Patin, N.J. Stoyer, J.F. Wild, and P.A. Wilk
|Dr. Yuri Ts. Oganessian discussing heavy element synthesis in the lab.|
|LLNL Super Heavy Element group members  include (left to right): Roger Henderson, Ken Moody, Mark Stoyer, Philip Wilk, Sarah Nelson, Julie Gostic and Dawn Shaughnessy.|
Periodic Table with Proposed Names for Elements 114 and 116 (PDF download)
About Superheavy Elements
What is a heavy element?
What is a superheavy element?
What is an atomic number?
What are isotopes?
How are new elements discovered?
What is a cyclotron?
What are some properties of artificially made elements?
What is the "island of stability"?
What is the "sea of instability"?
Why is discovering new superheavy elements important?
How can superheavy elements be used?
How long did it take to discover elements 113 and 115?
Why are the superheavy-element experiments conducted in Russia?
What special equipment is needed to discover superheavy elements?
When will the elements be named?
Why these names for elements 114 and 116?
A heavy element is an element with an atomic number greater than 92. The first heavy element is neptunium (Np), which has an atomic number of 93. Some heavy elements are produced in reactors, and some are produced artificially in cyclotron experiments.
The definition of superheavy elements (SHE) varies among different groups of people. We use the term term SHE to refer to those elements with an atomic number greater than or equal to 112. The first superheavy element is element 113, which has been recently discovered by a collaboration of scientists from the Lawrence Livermore National Laboratory and the Joint Institute of Nuclear Research in Russia. Like some of the heavy elements, superheavy elements are produced artificially in cyclotron experiments.
The atomic number refers to the number of protons in an elements nucleus. Each element has a unique atomic number and is known by that number until it receives an official name. For example, the two new superheavy elements 114 and 116 have 114 and 116 protons, respectively, in their nuclei.
Elements are defined by their atomic numbers or number of protons in the nucleus. Elements, however, have more than one isotope. An isotope contains varying numbers of neutrons in the nucleus. Gold, for example, has one stable isotope often denoted as . It has an atomic number of 79 (meaning 79 protons in the nucleus) and a mass number of 197, or the total number of neutrons and protons in the nucleus. Thus, there are 197 – 79 = 118 neutrons in this isotope. However, more than 30 isotopes of gold are known. Each isotope has its own decay characteristics and half-life. For example, , an isotope with one more neutron (119) that the stable isotope , has a half-life of 2.7 days and decays by beta-decay. A very different gold isotope, , has a half-life of 5 ms and decays by alpha-decay.
Several experimental techniques have been used to make new chemical elements. Some of these include heavy ion transfer reactions, cold or hot fusion evaporation reactions, neutron capture reactions, light-ion charged particle induced reactions, and even nuclear explosions. These techniques each have advantages and disadvantages making them suitable for studying nuclei in certain regions.
The types of nuclear reactions that have been successfully used to produce new elements in the last decade are cold fusion reactions and hot fusion reactions. Cold fusion reactions use beam and target nuclei that are closer to each other in mass in order to produce a compound nucleus (the complete fusion of one target nucleus with one beam nucleus) with generally lower excitation energy that typically requires evaporation of one or no neutrons. This generates fewer neutron-rich isotopes of an element that have higher survival probabilities with respect to fission, but have lower fusion probabilities. An example of this type of reaction is 70Zn + 208Pb → 277112 + 1n with a cross-section of ~1 picobarn.
Because the 112 isotope ultimately decays by α emission to known nuclei [namely isotopes of elements 102 (No) and 104 (Rf)], identification of this element is straightforward. Hot fusion reactions use more asymmetric beam and target nuclei, produce a compound nucleus with generally higher excitation energy that typically requires evaporation of three to five neutrons, generate more neutron-rich isotopes of an element, have lower survival probabilities with respect to fission, but have higher fusion probabilities. An example of this type of reaction is 48Ca + 244Pu → 288114 + 4n with a cross-section of ~1 pb. Because of the neutron-richness of this isotope of element 114, it never subsequently decays to any known isotope, and thus its identification is more problematic. Cold fusion reactions have been successful in producing elements 104—112 and hot fusion reactions have recently provided evidence for elements 113—118.
U400 cyclotron in Dubna, Russia
A cyclotron is a particle accelerator that boosts ions to very high velocities through a series of small kicks as the ions travel in a circular motion (or spiral). The cyclotron was invented at the University of California, Berkeley, by Ernest O. Lawrence , the namesake of the Lawrence Livermore National Laboratory.
Isotopes of various elements that are created artificially in accelerator experiments are unstable and radioactive. Once produced, these new isotopes begin to decay; that is, change into another isotope. The time required for half of an isotopes atoms to decay is called the isotopes half-life. As the atomic number of each new heavy element increases, the half-life typically decreases, meaning that new elements tend to decay more quickly. However, physicists in the 1960s predicted that this trend toward shorter half-lives would change around element 114. They thought that some elements around element 114 would have longer half-lives, forming an island of stability in the midst of a sea of highly unstable elements.
The "island of stability" refers to a predicted region of superheavy elements on the chart of nuclides with half-lives that are longer by several orders of magnitude than the half-lives of other superheavy elements. Half-lives for elements in the island of stability may range from seconds to minutes, while half-lives for other superheavy elements may be measured in micro- or nanoseconds. The existence of the island of stability was shown in 1998 with the discovery of the superheavy element 114. The island of stability is a specific subset of the superheavy elements, which is characterized by nuclei that have a spherical shape.
The "sea of instability" refers to a region of elements on the periodic table that are highly unstable. These elements have extremely short half-lives that may be measured in micro- or nanoseconds. (A nanosecond is the time it takes for light to travel one foot.) This region of unstable elements surrounds the island of stability.
Discovering new superheavy elements proves long-held nuclear theories regarding the existence of the island of stability and the ultimate limits of the periodic table of the elements. These discoveries also help scientists to better understand how nuclei are held together and how they resist the fission process. The skills that are acquired by conducting these heavy-element experiments can then be applied to solving national needs like stockpile stewardship and homeland security. For example, an improved understanding of the fission process will enable scientists to enhance the safety and reliability of the nations nuclear stockpile and nuclear reactors.
Like most scientific discoveries, researchers do not yet know the immediate practical applications of the discovery of elements 114 and 116. Previously discovered heavy elements are used in smoke detectors (americium), neutron radiography and neutron interrogation (curium and californium), and nuclear weapons (plutonium). Scientists expect that practical applications of elements 114 and 116 also exist and will be discovered in the future.
- Elements 113 and 115—The experiment began on July 14, 2003, and ended on August 10, 2003. In that time, four atoms of element 115 were produced that decayed after a given time, thereby producing element 113, which also decayed and so on. However, years of successful experiments, previous to the 115 and 113 discovery, were needed to show that the experiment could be successful. More than a year was then spent to clean the target material, ship it to Russia, make the target, and run the experiment. More than 20 atoms have been observed by 2010.
- Element 114—The first element 114 experiment lasted about one year, and two atoms were discovered during that time – more than 40 atoms have been observed by 2010.
- Element 116—The element 116 experiment also lasted about one year, and three atoms were discovered during that time – more than 25 atoms have been observed by 2010.
- Element 117—Production of element 117 took an incredible amount of international cooperation and patience, and over 2 years of effort. The 249Bk target material was produced during 250 days of irradiation in the Oak Ridge High Flux Isotope Reactor (HFIR) during 2008. Chemical separation and purification occurred in early 2009 and then the material was shipped to Dmitrovgrad, Russia for manufacture of the target. The bombardment of the target with 48Ca began in July 2009 and lasted for 150 days. Six atoms were observed and the results were published in April, 2010.
- Element 118—Element 118 was produced during two separate experiments, each one lasting for several months. A total of three atoms were discovered in both experiments combined.
We collaborate with our Russian colleagues because we share a similar passion for the study of heavy elements, and we bring complementary skills and resources to the solution of magnificent problems such as the confirmation of the existence of the "Island of Stability" and the characterization of the chemical properties of exotic elements. This collaboration has been very fruitful and stimulating—enabling each group to achieve more in a shorter period of time. This equipment is operated by the highly trained scientific staff at the Dubna laboratory.
There are three pieces of special equipment: (1) a cyclotron, which produces the intense beams of calcium-48 ions used to produce the superheavy elements; (2) a separator that separates the atoms of interest from everything else produced in these reactions; and (3) a detection system that can observe and record all of the events that take place during the experiment.
We don't know when the elements will be named. The naming of new elements is a long process governed by the International Union of Pure and Applied Chemistry (IUPAC). Any discovery of new elements must first be confirmed by an independent laboratory and established beyond a reasonable doubt. Afterwards, the research team that discovered the element is asked to propose a name and symbol for the element. The proposed name is then reviewed by a panel of experts and, if all goes well, finally approved by the IUPAC. This naming process can take many years. For example, element 110 was discovered in 1995 and received its name, darmstadtium (Ds), in 2003, while element 106 was discovered in 1974 but was not officially named as seaborgium (Sg) until 1997. Until elements 113 and 115 receive their official names, they will be known by their temporary IUPAC names: ununtrium (Uut) for element 113 and ununpentium (Uup) for element 115.
Element with atomic number 114 Flerovium (Fl) is proposed to be named in honor of Flerov Laboratory of Nuclear Reactions where the superheavy elements including element 114 were synthesized. Georgiy N. Flerov (1913 – 1990) – is a renowned scientist, physicist, author of the discovery of the spontaneous fission of uranium (1940, with Konstantin A. Petrzhak), pioneer in heavy-ion physics; founder in the Joint Institute for Nuclear Research the Laboratory of Nuclear Reactions (1957) that since 1991 is named after G.N. Flerov. Professor G.N. Flerov is known also for his fundamental works in various fields of physics that resulted in discovery of the new phenomena in properties and interactions of the atomic nuclei; playing of key role in establishment and development of the many areas of further research.
Element with atomic number 116 Livermorium (Lv) The name was chosen to honor Lawrence Livermore National Laboratory (LLNL, established in1952) located in the town of Livermore, California, United States of America. A group of researchers from this laboratory, along with the heavy element research group of the Flerov Laboratory of Nuclear Reactions (FLNR), participated in the work carried out in Dubna on the synthesis of superheavy elements, including element 116.
Related Web Pages
- Discovery of Elements 114 and 116
- Livermore Scientists Team with Russia to Discover Element 118
- News Release about Discovery of Element 118
- Heavy Element Group Publications